کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7720846 | 1497504 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mn-based borohydride synthesized by ball-milling KBH4 and MnCl2 for hydrogen storage
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
In this work, a mixed-cation borohydride (K2Mn(BH4)4) with P21/n structure was successfully synthesized by mechanochemical milling of the 2KBH4-MnCl2 sample under argon. The structural and thermal decomposition properties of the borohydride compounds were investigated using XRD, Raman spectroscopy, FTIR, TGA-MS and DSC. Apart from K2Mn(BH4)4, the KMnCl3 and unreacted KBH4 compounds were present in the milled 2KBH4-MnCl2. The two mass loss regions were observed for the milled sample: one was from 100 to 160 °C with a 1.6 ± 0.1 wt% loss (a release of majority hydrogen and trace diborane), which was associated with the decomposition of K2Mn(BH4)4 to form KBH4, boron, and finely dispersed manganese; the other was from 165 to 260 °C with a 1.9 ± 0.1 wt% loss (only hydrogen release), which was due to the reaction of KBH4 with KMnCl3 to give KCl, boron, finely dispersed manganese. Simultaneously, the formed KCl could dissolve in KBH4 to yield a K(BH4)xCl1âx solid solution, and also react with KMnCl3 to form a new compound K4MnCl6.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 5, 4 February 2014, Pages 2194-2200
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 5, 4 February 2014, Pages 2194-2200
نویسندگان
Ruixia Liu, David Book,