کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
77296 49162 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of alkaline earth metals on catalytic performance of HY zeolite for alkylation of α-methylnaphthalene with long-chain olefins
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Effect of alkaline earth metals on catalytic performance of HY zeolite for alkylation of α-methylnaphthalene with long-chain olefins
چکیده انگلیسی

Friedel–Crafts alkylations of α-methylnaphthalene with long chain alkenes (C11–12) in liquid–solid phase over alkaline earth metal oxides like MgO, CaO, SrO and BaO modified HY zeolite catalysts have been investigated. Effect of BaO impregnated amount on the reaction was investigated. Results show that 1%BaO modified HY zeolite (1%BaO–HY) exhibits outstanding catalytic performances, and the stability of catalyst may be improved when modified by optimal alkaline earth metal oxide. Moreover, effects of reaction conditions like reaction temperature, volume hour space velocity (VHSV) and time on stream (TOS) on the 1%BaO–HY promoted alkylation were also studied. It is found that Brönsted acid centre is the main catalytic active centre, and Lewis acidic sites have an obvious promotion effect on reaction performance for the alkylation reaction.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 94, Issues 1–3, 8 September 2006, Pages 105–112
نویسندگان
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