کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7732015 | 1497946 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dithionite/air direct ion liquid fuel cell
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Dithionite/air direct ion liquid fuel cell Dithionite/air direct ion liquid fuel cell](/preview/png/7732015.png)
چکیده انگلیسی
The feasibility of an alkaline S2O42â/air-fuel cell was evaluated at room temperature, using a cell with an anion exchange membrane and a platinum oxygen reduction reaction catalyst. The tests performed were open circuit voltage analysis, linear sweep voltammetry, discharge analysis and electrochemical impedance spectroscopy (EIS) with registration of anode half-cell potential. With 0.85 M Na2S2O4 in 2 M KOH, the cell achieved a maximum power density of 2 mW cmâ2, and the open circuit cell voltage was about 0.9 V. In a potentiostatic discharging at 0.2 V cell voltage, an energy efficiency of 12.3% was achieved at an energy density of 8.6 Wh Lâ1. The low power density was mainly due to the low reaction kinetics of dithionite oxidation at graphite electrodes. The low energy efficiency was mainly caused by a low cathode potential, which probably resulted from mixed potential formation and the low anode kinetics.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 286, 15 July 2015, Pages 232-238
Journal: Journal of Power Sources - Volume 286, 15 July 2015, Pages 232-238
نویسندگان
Jens Noack, Jens Tübke, Karsten Pinkwart,