کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7748112 1498739 2014 21 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural chemistry of metal coordination complexes at high pressure
ترجمه فارسی عنوان
شیمی سازه ای از کمپلکس های هماهنگی فلز در فشار بالا
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی
The application of pressures of up to about 10 GPa may induce significant geometric, configurational, conformational and packing changes in molecular solids. This review highlights and describes recent advances in high pressure studies of coordination complexes, many of which have been conducted at synchrotrons or other central facilities. The main focus is on the wide range of geometric changes which occur with pressure. In some cases these changes have associated physical effects, and the review describes materials exhibiting negative linear compressibility, spin cross-over phenomena, magnetism and molecular conduction, as well as detailing the exciting possibilities for future developments in this area of research.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volumes 277–278, 1 October 2014, Pages 187-207
نویسندگان
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