Assembly of three organic-inorganic hybrid supramolecular materials based on reduced molybdenum(V) phosphates

As new linking unit, Cu(H2O)3, Ni(H2O), and {Ni2(H2O)10Na(PCA)2} are introduced into {TM(P4Mo6)2} reaction systems to assemble three supramolecular materials under hydrothermal conditions via changing organic ligand and transition metal.