The structures and properties of the new two-dimensional inorganic-organic hybrid materials based on the molybdate chains

In complex 1, The Co ion is six coordinated by four oxygen atoms from two Mo6O20 and two water molecules, and two N atoms from two different ligand. It is noticeable that there is an one-dimensional chain molybdate, which is combined by O-Mo-O, then the chain parallel with each other, the Mo6 anion acts as a bidentate ligand providing O7 atoms to bridge CoII ions to form a 2D inorganic layer. Finally every nets become 3D structure by hydrogen bond.