کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
77884 49309 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Energy level diagram around Ge-rich grain boundaries in Cu2Sn1-xGexS3 (CTGS) thin-film solar cells
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Energy level diagram around Ge-rich grain boundaries in Cu2Sn1-xGexS3 (CTGS) thin-film solar cells
چکیده انگلیسی


• We carried out 3-dimensional atom probe analysis around grain boundaries (GBs) of CTGS.
• Ge concentration at the GBs was higher than that inside the grains.
• The Ge-richer conposition shifts the conduction band minimum to higher.
• This suppresses recombination of photo-generated carriers in CTGS solar cells.

Using a 3-dimensional atom probe (or atom probe tomography) method, we measured the composition ratios around the grain boundaries of Cu2Sn1-xGexS3 (CTGS) films used for the bottom cells of thin-film double-junction solar cells. We found that the Ge composition ratio at the grain boundaries in the CTGS films was higher than that inside the grains when the films were fabricated by co-sputtering depositions of Cu and Sn followed by sulfurizations with S and GeS2 vapors. We also evaluated the bandgaps of Cu2Sn1-xGexS3 with changing the x value by measuring external quantum efficiency spectra of the solar cells. From these results, we have obtained the energy level diagram around the grain boundaries, and revealed that the conduction band minimum at the grain boundaries is 0.05 eV higher than that inside the grains, which suppresses recombination of photogenerated carriers.

Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solar Energy Materials and Solar Cells - Volume 134, March 2015, Pages 1–4
نویسندگان
, , , , , , ,