کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7790419 | 1500644 | 2014 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cellulose hydrogels prepared from micron-sized bamboo cellulose fibers
ترجمه فارسی عنوان
هیدروژل های سلولز از الیاف سلولز بامبو ساخته شده اند
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کلمات کلیدی
هیدروژل سلولز، سونوگرافی، دیالیز، خواص رئولوژیکی،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
We demonstrated for the first time that dimensionally stable hydrogels could be obtained from bamboo pulp fibers through dialysis against distilled water followed by a short time of ultrasonic treatment. Micron-sized short fibers rather than cellulose nanofibrils constituted the majority of fibers in the hydrogels. During the pulping process with HNO3 and KClO3, carboxylic groups could be introduced to cellulose due to the mild oxidation of hydroxyl groups. When presented in aqueous NaOH, the carboxylic groups could be converted into their sodium salt form. The subsequent dialysis treatment against water made the negatively charged COOâ groups extensively exposed. The negatively charged cellulose fibers could induce considerable electrostatic repulsion between them, which was discovered to govern the formation of hydrogels. In addition, it was revealed that homogeneous hydrogels could be formed when the pH was at 7, 9 and 11. However, when salt was added, no dimensionally stable hydrogel was obtained.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 114, 19 December 2014, Pages 166-169
Journal: Carbohydrate Polymers - Volume 114, 19 December 2014, Pages 166-169
نویسندگان
Xiaofang Zhang, Yaru Wang, Canhui Lu, Wei Zhang,