کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7807327 | 1501653 | 2018 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Crystal structure of 9,9â²-(4,4â²-(silinane-1,1-diyl)bis(4,1-phenylene))bis(9H-carbazole) and its photophysical and electrochemical properties
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The title compound 9,9â²-(4,4â²-(silinane-1,1-diyl)bis(4,1-phenylene))bis(9H-carbazole) (6-bisCz) has been designed and prepared to investigate its crystal structure and photophysical and electrochemical properties. 6-bisCz is crystallized in the centrosymmetric space group Pâ1. Interestingly, the asymmetric unit contains two molecules (Zâ²â¯=â¯2), and hence, the entire cell contains four units (Zâ¯=â¯4). The central silicon atom was arranged in pseudo-tetrahedral geometry defined by the two ipso-carbon atoms of the phenyl groups and two carbon atoms in the endocyclic hexyl ring, with average bond angles of 104.5(1)° and 108.5(1)°, respectively. UV/Vis absorption and photoluminescence spectra showed that the central silicon atom successfully disconnected electronic communication between the two peripheral phenylcarbazole units, yielding similar absorption and emission spectra to an unsubstituted carbazole monomer. The influence of the central silicon atom between the two phenylcarbazole units is also simulated by density functional theory calculations. Finally, electrochemical properties of 6-bisCz were investigated, and the analysis shows that an electropolymerized film was successfully formed during the electrochemical process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1164, 15 July 2018, Pages 23-27
Journal: Journal of Molecular Structure - Volume 1164, 15 July 2018, Pages 23-27
نویسندگان
Yoona Park, Joori Jung, Hani Jeon, Sunhee Lee, Won-Sik Han,