کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7809283 1501696 2016 20 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Tertiary to secondary reduction of aminomethylphosphane derived from 1-ethylpiperazine as a result of its coordination to ruthenium(II) centre - The first insight into the nature of process
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Tertiary to secondary reduction of aminomethylphosphane derived from 1-ethylpiperazine as a result of its coordination to ruthenium(II) centre - The first insight into the nature of process
چکیده انگلیسی
Introduction of tertiary aminomethylphosphane P{CH2N(CH2CH2)2NCH2CH3}3 to methanolic solution of [Ru(η5-C5H5)Cl(PPh3)2] and NaBF4, instead of substitution of the chloride leads to cleavage of aminomethylphosphane's PCH2 bond and formation of complex [Ru(η5 C5H5)PH{CH2N(CH2CH2)2NCH2CH3}2(PPh3)2]BF4.142
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1121, 5 October 2016, Pages 104-110
نویسندگان
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