کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7810204 | 1501763 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Assessment of the molecular structure of natrodufrénite - NaFe2+Fe53+(PO4)4(OH)6·2(H2O), a secondary pegmatite phosphate mineral from Minas Gerais, Brazil
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The mineral natrodufrénite a secondary pegmatite phosphate mineral from Minas Gerais, Brazil, has been studied by a combination of scanning electron microscopy and vibrational spectroscopic techniques. Electron probe analysis shows the formula of the studied mineral as (Na0.88Ca0.12)â1.00(Fe0.722+Mn0.11Mg0.08Ca0.04Zr0.01Cu0.01)â0.97(Fe4.893+Al0.02)â4.91(PO4)3.96(OH6.15F0.07)6.22â
2.05(H2O). Raman spectroscopy identifies an intense peak at 1003 cmâ1 assigned to the PO43- ν1 symmetric stretching mode. Raman bands are observed at 1059 and 1118 cmâ1 and are attributed to the PO43- ν3 antisymmetric stretching vibrations. A comparison is made with the spectral data of other hydrate hydroxy phosphate minerals including cyrilovite and wardite. Raman bands at 560, 582, 619 and 668 cmâ1 are assigned to the ν4PO43- bending modes and Raman bands at 425, 444, 477 and 507 cmâ1 are due to the ν2PO43- bending modes. Raman bands in the 2600-3800 cmâ1 spectral range are attributed to water and OH stretching vibrations. Vibrational spectroscopy enables aspects of the molecular structure of natrodufrénite to be assessed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1051, 5 November 2013, Pages 265-270
Journal: Journal of Molecular Structure - Volume 1051, 5 November 2013, Pages 265-270
نویسندگان
Andrés López, Ray L. Frost, Yunfei Xi, Ricardo Scholz, Fernanda Maria Belotti, Ãrika Ribeiro,