کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7810399 | 1501766 | 2013 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)4]
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new organic-inorganic hybrid pentaborate [C6H14N][B5O6(OH)4] (1) has been synthesised hydrothermally in aqueous solution and characterised by single-crystal X-ray diffraction, FT-IR, DTA-TG and photoluminescence spectroscopy. It crystallizes in the monoclinic system, space group P21/c, with the lattice constants of a = 9.463 (2) Ã
, b = 14.005 (3) Ã
, c = 10.642 (2) Ã
, and β = 93.82(3)°. The structure consists of isolated [B5O6(OH)4]â groups interlinked by protonated cyclohexylamine via hydrogen bonding. Blue photoluminescence of 1 is observed upon UV excitation, which can be further enhanced and modified to near-white emission by thermal treatment. The maximum emissions and peak shapes of 1-250 °C are also tunable with various excitation wavelengths in the region of 350-470 nm. This compound provides a novel example of organically templated borate materials potential for display and lighting applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1048, 24 September 2013, Pages 1-5
Journal: Journal of Molecular Structure - Volume 1048, 24 September 2013, Pages 1-5
نویسندگان
Wenjiao Luo, Yonggang Wang, Ting Wen, Hao Zhang, Xiaohuan Lin, Yingxia Wang, Fuhui Liao, Jianhua Lin,