کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7832103 1503287 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Multinuclear Solid-state NMR Study on the Calcium Ions Extracting Process of Layered Sodium Disilicate SKS-6
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Multinuclear Solid-state NMR Study on the Calcium Ions Extracting Process of Layered Sodium Disilicate SKS-6
چکیده انگلیسی
The reactions of layered sodium disilicate SKS-6 and calcium chloride solution with invariant concentration reacted for different reaction times were studied using solid-state 1H, 29Si, and 23Na nuclear magnetic resonance (NMR) spectroscopy as well as X-ray powder diffraction technique. On the basis of the experimental results the calcium ions extracting process of SKS-6 was shown to be rapid ions substitution of sodium ions by calcium ions. After substitution, calcium ions combined with the SiO4 tetrahedrons in SKS-6, and the ordering of the silicate layer was decreased to a certain extent, with the survival of original layered structure. Ion substitution rapidly proceeded and almost was completed within 1 min because prolonging the reaction time introduced no obvious variation in it. Prolonging the reaction time just prompted the hydrolysis of bridging as well as nonbridging oxygen atoms in SKS-6, and simultaneously changed the chemical circumstance of sodium ions in the newly formed kanemite phase.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Acta Physico-Chimica Sinica - Volume 23, Issue 6, June 2007, Pages 867-872
نویسندگان
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