کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7839675 | 1505859 | 2018 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Doping concentration-independent optical thermometric properties in Stark sublevels-based Er3+-activated BaGd2O4 luminescent thermometers
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Doping concentration-independent optical thermometric properties in Stark sublevels-based Er3+-activated BaGd2O4 luminescent thermometers Doping concentration-independent optical thermometric properties in Stark sublevels-based Er3+-activated BaGd2O4 luminescent thermometers](/preview/png/7839675.png)
چکیده انگلیسی
We reported a facile strategy to modify the sensor sensitivities of Er3+-doped BaGd2O4 phosphors by simultaneously modulating the dopant concentration and utilizing the proper Stark sublevels. Under the excitation of 377â¯nm, visible emissions originating from the Stark sublevels of Er3+ ions (2H11/2(1), 2H11/2(2), 4S3/2(1), 4S3/2(2), 4F9/2(1) and 4F9/2(2)) were detected in all the prepared samples. The optimal doping concentration for the Er3+ ions in the BaGd2O4 host lattice was 2â¯mol% and the electric dipole-dipole interaction can contribute to the concentration quenching mechanism. By utilizing the fluorescence intensity ratio technique, the optical thermometric properties of the obtained phosphors in the temperature range of 288-483â¯K were studied based on the thermally coupled levels of 2H11/2(1)/4S3/2(1), 2H11/2(2)/4S3/2(1), 2H11/2(1)/4S3/2(2), 2H11/2(2)/4S3/2(2) and 2H11/2/4S3/2. The maximum relative sensor sensitivities of the resultant compounds based on the Stark levels of 2H11/2(1)/4S3/2(2) were much higher than that based on the 2H11/2/4S3/2 ordinary thermally coupled levels. Furthermore, the relative sensor sensitivities of the synthesized phosphors were insensitive to the doping concentration and its maximum value was up to 0.0175â¯Kâ1 at 288â¯K. These characteristics demonstrated that the Er3+-doped BaGd2O4 material system was suitable for optical thermometers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 203, November 2018, Pages 172-178
Journal: Journal of Luminescence - Volume 203, November 2018, Pages 172-178
نویسندگان
Peng Du, Jae Su Yu,