کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7840025 | 1505861 | 2018 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Eco-friendly polydimethylsiloxane-based self-supporting film containing europium-polyoxometalate: A flexible luminescent material for white light generation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Lanthanide (Ln3+)-doped suitable matrices exhibit unique luminescent properties which are important for applications in optoelectronic devices. Most of the Ln3+-based luminescent materials are, however, prepared in powder form using suitable robust inorganic host matrices. These matrices, often, experience lack of flexibility which is important for many applications such as LEDs and wearable devices, among others. To address this aspect, we report the preparation of flexible and highly transparent luminescent membranes based on polydimethylsiloxane-hydroxyurethanes (PDMSUr) as the hybrid framework and Europium-polyoxometalate (Eu(PW11)2) complex as the luminescent component. The PDMSUr, besides acting as green, transparent and flexible matrix, is found to increase the emission decay lifetime (from 1.5â¯ms to 3.0â¯ms) when Eu(PW11)2 is incorporated in the hybrid matrix. Moreover, upon UV excitation, the matrix exhibits a broader emission around 450â¯nm which, together with the characteristic emission of Eu3+ ions, leads to the generation of white light.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 201, September 2018, Pages 384-389
Journal: Journal of Luminescence - Volume 201, September 2018, Pages 384-389
نویسندگان
Mateus Batista Simões, Sajjad Ullah, Chanchal Hazra, Michel Wong Chi Man, Sidney José Lima Ribeiro, Ubirajara Pereira Rodrigues-Filho,