کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7840436 | 1505866 | 2018 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Comparison of the spectroscopic characteristics of uranium status when U(III) in LiCl-KCl eutectic melt is leached out with water and ionic liquid
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
The physicochemical properties of U(III) in molten salt in contact with ionic liquid and water were investigated to obtain better understandable information on the long-term storage of waste salt remaining from pyrochemical processing. UCl3 in LiCl-KCl eutectic melt was added into appropriate room-temperature ionic liquid and water, and determination of the oxidation state of uranium (U) in LiCl-KCl eutectic melt was achieved using spectroscopic methods. The addition of UCl3 in LiCl-KCl eutectic melt into the ionic liquid provided the same absorption spectrum as that obtained from the solvation of UCl3 by LiCl-KCl eutectic melt at 450 °C except for much less absorption peak intensities. The room-temperature ionic liquid of 1-hexyl-3-methyl-imidazolium chloride (HMICl) used in this research did not cause any oxidation or reduction of the U(III), as the other reported ionic liquids did. The U(III) in LiCl-KCl eutectic melt was stable in an HMICl ionic liquid and unstable in water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 196, April 2018, Pages 302-305
Journal: Journal of Luminescence - Volume 196, April 2018, Pages 302-305
نویسندگان
Hee-Jung Im, Jei-Won Yeon,