کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7841927 | 1506504 | 2018 | 33 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Micelle formation by amine-based CO2-responsive surfactant of imidazoline type in an aqueous solution
ترجمه فارسی عنوان
تشکیل مایکلل توسط سورفاکتانت واکنش پذیر دی اکسیدکربن نوع ایمیدازولین در محلول آبی تشکیل شده است
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
This study presents the synthesis of a CO2-responsive surfactant namely 2âalkylâ1âhydroxyethyl imidazoline (HEAnIBs nâ¯=â¯16, 18, 20), which exhibits satisfactory surface and adsorption properties. The micelle formation and adsorption of the above imidazoline based surfactant in aqueous solution were studied in this work. CMC, the effectiveness of surface tension reduction, the maximum surface excess concentration, the minimum area occupied per surfactant molecule at the air/water interface, and the micelle aggregation number were obtained by measuring surface tension. Dynamic light scattering indicates that when the surfactant concentration is 1.2 times the CMC, the hydrodynamic radii of the three surfactants studied were almost equal to 8â¯nm. Electrical conductivity measurements indicate the micellization of surfactants in aqueous solution. In addition, typical thermodynamic parameters, including ÎGm0, ÎGads0, ÎHm0, ÎSm0, ÎHmA, ÎSmA, and ÎCp,m0 were evaluated. The thermodynamic parameters show that micelle formation is entropy-and-enthalpy co-driven from 298â¯K to 318â¯K. We expect to elucidate the self-assembly of CO2-responsive surfactant in an aqueous solution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 268, 15 October 2018, Pages 875-881
Journal: Journal of Molecular Liquids - Volume 268, 15 October 2018, Pages 875-881
نویسندگان
Mingwei Zhao, Haonan He, Caili Dai, Xuepeng Wu, Yue Zhang, Yongping Huang, Chenglin Gu,