کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7993041 | 1516150 | 2018 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Tuning of physical properties of Fe7(PO4)6 by sodium intercalation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
The sodium intercalation of mixed - valence iron phosphate Fe32+Fe43+(PO4)6 results in drastic transformation of its physical properties. The parent compound Fe7(PO4)6 reaches magnetically ordered state through succession of phase transitions at TN1â¯=â¯45.5â¯K and TN2â¯=â¯16â¯K marked by sharp singularities in both specific heat Cp and magnetic susceptibility Ï. The introduction of sodium suppresses the formation of antiferromagnetic state down to TNâ¯=â¯33â¯K in Na0.65Fe7(PO4)6. The low temperature phase transition in this compound smears being substituted by broad anomalies in magnetization and specific heat related to the spin/charge disorder effects. The sharp well resolved electron spin resonance spectra in parent material transform into asymmetric broad line in sodium - intercalated substance. The dielectric permittivity ε of Fe7(PO4)6 demonstrates a kink at TN2, while no singularity marks TN1. No features accompany magnetic phase transition in dielectric property of Na0.65Fe7(PO4)6 but ε reaches the relaxation maxima at high temperatures which can be attributed to the freezing of sodium ions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 744, 5 May 2018, Pages 600-605
Journal: Journal of Alloys and Compounds - Volume 744, 5 May 2018, Pages 600-605
نویسندگان
Ekaterina Kozlyakova, Igor Danilovich, Anatoliy Volkov, Konstantin Zakharov, Olga Dimitrova, Elena Belokoneva, Larisa Shvanskaya, Elena Zvereva, Dmitry Chareev, Olga Volkova, Alexander Vasiliev,