کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8125276 | 1522778 | 2018 | 26 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Organic bases, carbon dioxide and naphthenic acids interactions. Effect on the stability of petroleum crude oil in water emulsions
ترجمه فارسی عنوان
پایه های ارگانیک، دی اکسید کربن و متابولیسم های نافنیک. تأثیر بر پایداری نفت خام نفتی در امولسیون آب
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
زمین شناسی اقتصادی
چکیده انگلیسی
Understanding the mechanisms that lead to the formation of petroleum crude oil in water emulsion is fundamental for the development of sustainable exploitation procedures and efficient oil spills remediation technologies. In this study we surveyed the effectiveness of different nitrogen-containing organic bases in promoting emulsification through the interaction with the naphthenic acid fraction present in crude oil. It was found that bulky secondary amines were the most effective, able to stabilize the emulsion at 10â¯wt% of oil content for more than 20â¯min, and the emulsion at 40â¯wt% for more than 5â¯h. Interfacial tension measurements indicated that the interaction was effective even when naphtenic acids were dosed at very low levels (total acid number lass than 0.3). It was also observed that a successive addition of carbon dioxide to the system readily induced the breaking of the emulsion, probably by affecting the equilibrium involved in the formation of the naphthenates stabilizing species. In the light of these findings, we tested polyethylene glycols bearing a terminal amino moiety as a new class of CO2 responsive emulsifiers suitable for the petroleum industry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Petroleum Science and Engineering - Volume 163, April 2018, Pages 177-184
Journal: Journal of Petroleum Science and Engineering - Volume 163, April 2018, Pages 177-184
نویسندگان
Francesco Saliu, Roberto Della Pergola,