کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
866169 | 1470944 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reusable DNA-functionalized-graphene for ultrasensitive mercury (II) detection and removal
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Mercury is a bioaccumulative and highly toxic heavy metal. Thus, the removal and detection of Hg2+ from the environment is a major challenge. This paper reports a novel bio-nanomaterial for the simultaneous determination and removal of Hg2+ with the use of rGO-Fe3O4 functionalized with Hg2+-specific thymine oligonucleotide (T-DNA). T-DNA interacts with Hg2+ and changes from having a random coil into a hairpin structure, thereby increasing the fluorescence of SYBR Green I. Such fluorescence turn-on process allows the detection of Hg2+ in the concentration range of 1-20Â ng/mL, with a detection limit of 0.82Â ng/mL. Removal is achieved by exploiting the T-Hg2+-T base pairs and the large surface area of graphene; these bio-nanocomposites exhibit excellent removal efficiency (over 80%) and rapid separation from the aqueous solution. Moreover, bio-nanomaterials can be regenerated after a simple treatment. The proposed method also demonstrates the evident practicability of the simultaneous detection and removal of Hg2+ in lake water samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Biosensors and Bioelectronics - Volume 87, 15 January 2017, Pages 129-135
Journal: Biosensors and Bioelectronics - Volume 87, 15 January 2017, Pages 129-135
نویسندگان
Yanchen Liu, Xiangqing Wang, Hui Wu,