کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9585178 | 1392333 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Energy relaxation through the Ï*-state in C, F and O K-shell excited CF3COCH3
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Total photoabsorption spectra of CF3COCH3 were measured in the C, F and O K-shell regions and the peak assignments were tentatively given. The K-shell electrons of C, F and O atoms were selectively excited into the Ï* orbital. The kinetic energy (KE) distribution of CF3+ formed through the Ï* states gave the maxima at KEÂ =Â 0 and 0.43Â eV. The yield of CF3+ with KEÂ =Â 0Â eV increased from 10 to 50% by changing the excitation sites from F 1s to O 1s. This finding was reasonably understood by considering that intramolecular energy flows from the initially excited K-shell electron to vibrational modes of CF3 group. The KE distribution of CH3+ showed a mirror image of that for CF3+.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 143, Issue 1, April 2005, Pages 21-27
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 143, Issue 1, April 2005, Pages 21-27
نویسندگان
T. Ibuki, K. Okada, M. Takahashi, S. Samori, T. Goya, Y. Senba, H. Yoshida, A. Hiraya, K. Ohno,