کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9586297 | 1505940 | 2005 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The Eu3+ charge transfer energy and the relation with the band gap of compounds
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The Eu3+ charge transfer energy and the relation with the band gap of compounds The Eu3+ charge transfer energy and the relation with the band gap of compounds](/preview/png/9586297.png)
چکیده انگلیسی
The location of the energy levels of any of the 13 divalent lanthanides in oxide or fluoride compounds relative to the top of the valence band or the bottom of the conduction band can be obtained by using only three host dependent parameters: (1) the energy of charge transfer from the top of the valence band to Eu3+, (2) the redshift of the first 4fâ5d transition in divalent lanthanide ions, (3) the energy of charge transfer from the top of the valence band to the bottom of the conduction band. These three parameters were determined for a large collection of compounds by re-analyzing and retrieving data from literature on optical absorption and luminescence excitation spectra. Data are presented and a first analysis performed. Special attention is given to the systematic behavior in the energy of charge transfer (CT) to Eu3+ with (1) type of anions present in the compound, (2) the strength of binding of valence band electrons, and (3) the size of the site occupied. Also relationships between the CT energy and the band gap energy are explored.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 111, Issues 1â2, 1 January 2005, Pages 89-104
Journal: Journal of Luminescence - Volume 111, Issues 1â2, 1 January 2005, Pages 89-104
نویسندگان
P. Dorenbos,