کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9586327 | 1505936 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of Al3+ and Ti4+ ions on the laser reduction of Sm3+ ion in glass
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effect of Al3+ and Ti4+ ions on the laser reduction of Sm3+ ion in glass Effect of Al3+ and Ti4+ ions on the laser reduction of Sm3+ ion in glass](/preview/png/9586327.png)
چکیده انگلیسی
Femtosecond laser pulses were used to change the valence of Sm3+ ions doped in silicate glasses consisting of Al2O3 and TiO2. When doped in TiO2-SiO2 glass, no change was observed in Sm3+ ions by laser irradiation. On the other hand, Sm3+ ions were reduced to Sm2+ in Al2O3-containing glasses. Fluorescence line-narrowing spectra indicate that Ti4+ ions are dissolved in silica network and occupy the tetrahedral site forming Si-O-Ti bonds, while Al3+ ions occupy tetrahedral and octahedral sites. The laser irradiation carries to form the hole-defect centers in the oxygen ions in the Al-O octahedral. The released electrons from oxygen ions are captured in the nearest neighboring Sm3+ ions, resulting in the formation of Sm2+. On the other hand, in the Ti4+-containing glasses, the electrons are trapped in Ti4+ ions and no Sm2+ ions are formed. The fluorescence properties of the Sm2+ ions and defect centers were compared from the time-resolved fluorescence spectra.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 114, Issues 3â4, September 2005, Pages 178-186
Journal: Journal of Luminescence - Volume 114, Issues 3â4, September 2005, Pages 178-186
نویسندگان
Masayuki Nogami, Go Kawamura, Gil Jae Park, Hongpeng You, Tomokatsu Hayakawa,