کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9605565 | 44095 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photophysical properties of safranine and phenosafranine
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Photophysical properties of safranine and phenosafranine Photophysical properties of safranine and phenosafranine](/preview/png/9605565.png)
چکیده انگلیسی
The triplet quantum yield of the dyes safranine and phenosafranine was determined in methanol and acetonitrile by laser flash photolysis (LFP) and laser induced opto-acoustic spectroscopy (LIOAS). The excited singlet properties of both dyes were also determined in the two solvents. The LFP determination of the triplet yield was carried out by actinometric determination of the product ΦTÉT and independent estimation of ÉT by the singlet depletion method and by energy transfer using anthracene as energy donor. The results of the three methodologies coincide within the experimental error. The values of ΦT are in the range 0.21-0.50, and in the case of phenosafranine are considerably higher than those previously reported in the literature. An interesting outcome is that the results of LIOAS determination agree with those of LFP within the confidence interval.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 173, Issue 2, 1 July 2005, Pages 115-120
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 173, Issue 2, 1 July 2005, Pages 115-120
نویسندگان
MartÃn F. Broglia, MarÃa L. Gómez, Sonia G. Bertolotti, Hernán A. Montejano, Carlos M. Previtali,