کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9605676 | 44182 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of complexation on the photochromism of 5â²-(benzothiazol-2-yl)spiroindolinonaphthooxazines in polar solvents
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بیو مهندسی (مهندسی زیستی)
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چکیده انگلیسی
Complexation of Ni(II), Co(II) and Zn(II) with the photomerocyanines obtained under steady irradiation of spiroindolinonaphthooxazines containing benzothiazolyl substituent in the naphthooxazine moiety induces a slight hypsochromic shift of its visible absorption band and drastically slows down its thermal bleaching in the dark. As a result, the relaxation time at 20°C ranges from 2 to 42 min, the actual value depending on the metal ion and compound. High 'colourabilities' up to 5 Ã 104 Mâ1 cmâ1 (É = 6 Ã 104 Mâ1 cmâ1) are calculated from the absorbance values obtained by extrapolation to t = 0 of the room temperature linearly descending kinetic curves ln A/t. Complexation with Ni(II), Co(II) and Zn(II) allows the spiroindolinonaphthooxazines to isomerize to their open-coloured form even under dark conditions giving a complex spectroscopically identical to the photoinduced product and greatly increasing its lifetime to several days.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 171, Issue 2, 30 April 2005, Pages 153-160
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 171, Issue 2, 30 April 2005, Pages 153-160
نویسندگان
Bojana G. Jeliazkova, Stela Minkovska, Todor Deligeorgiev,