کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9617534 | 49164 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mid-infrared spectroscopic studies of alkali-activated fly ash structure
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
Infrared spectroscopic techniques were used in the present study to acquire a deeper understanding of mid-range order in the alkaline aluminosilicate (zeolite precursor) formed in the alkali activation of fly ash. Experiments were conducted with three type F fly ashes containing different proportions of vitreous and crystalline (primarily mullite and quartz) phases, activated with an 8 M solution of NaOH. All the mixes were alkali activated at 85 °C for the following reaction times: 2 h, 5 h, 8 h, 20 h and 7 days. The results indicate that the amount of alkaline silicoaluminate formed as the main reaction product, and its Si/Al ratio, induce a shift in the T-O stretching band appearing at 950-1100 cmâ1. Moreover, the presence of zeolite-type crystalline phases generates substantial changes in the 800-500 cmâ1 area of the spectra. Selective chemical attacks were used to facilitate identification of the spectra bands.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 86, Issues 1â3, 28 November 2005, Pages 207-214
Journal: Microporous and Mesoporous Materials - Volume 86, Issues 1â3, 28 November 2005, Pages 207-214
نویسندگان
A. Fernández-Jiménez, A. Palomo,