کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9617856 | 49182 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Carbon-based molecular sieve membranes for gas separation by inductively-coupled-plasma chemical vapor deposition
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Carbon-based molecular sieve (CMS) films for gas separation have been deposited on porous Al2O3 disks using hexamethyldisiloxane (HMDSO) by a remote inductively-coupled-plasma (ICP) chemical vapor deposition (CVD) method. The H2/N2 selectivities of the as-deposited films falled into the range of 5-10, higher than the Knudsen diffusion selectivity, 3.7. After pyrolysis of the as-deposited film at 873 K, the permeance increased by one order of magnitude with no significant change of the selectivity. A surface treatment method was further employed by bombarding the as-deposited film with high energy ions of HMDSO. After pyrolysis at 823 K, the surface-treated film exhibits a very significant increase of H2/N2 selectivity without any reduction of the permeance. The H2/N2 selectivity could reach 30-45 with an extremely high permeance around 2 Ã 10â6 mol mâ2 sâ1 Paâ1 at 423 K. The O2/N2 selectivity reached 3.8 and the O2 permeance was about 2 Ã 10â7 mol mâ2 sâ1 Paâ1 at 298 K. Therefore, a new method for preparing carbon-based molecular sieve membranes has been introduced by combining the surface treatment with high energy ion bombardment and the subsequent high temperature pyrolysis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 77, Issues 2â3, 26 January 2005, Pages 167-174
Journal: Microporous and Mesoporous Materials - Volume 77, Issues 2â3, 26 January 2005, Pages 167-174
نویسندگان
Liang-Jun Wang, Franklin Chau-Nan Hong,