کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9675723 | 1454105 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The influence of electrolyte ions on the interaction forces between polystyrene surfaces
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The forces between a flat polystyrene film and a polystyrene sphere have been measured in water and solutions of KCl and KOH. All force-distance curves show at distances >5-50 nm an electrical double-layer repulsion whose range and strength depend on the electrolyte concentration. The electrical double-layer potential at the polystyrene surface coincides with its zeta potential. An attractive force of variable range and strength dominates at shorter distances in water, KCl concentrations up to 10â2 M and a 10â5 M KOH solution. We attribute it to the existence of air nanobubbles on the polymer surface. It is not affected by the KCl concentration. In KOH concentrations â¥10â4 M, the attraction disappears. Instead, an additional “soft” steric repulsion occurs at distances <5-20 nm.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 264, Issues 1â3, 15 August 2005, Pages 157-165
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 264, Issues 1â3, 15 August 2005, Pages 157-165
نویسندگان
Astrid Drechsler, Karina Grundke,