کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9675812 | 1454107 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrodeposition of monodisperse copper nanoparticles on highly oriented pyrolytic graphite electrode with modulation potential method
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
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چکیده انگلیسی
Copper nanoparticles with size of 51Â nm and R.S.D.dia of 10% can be obtained by modulation potential electrodeposition: first, a â0.8Â VÂ ÃÂ 120Â ms potential step was used to nucleate copper particles on highly oriented pyrolytic graphite (HOPG) electrode surface, where nuclei with a supercritical size were formed, secondly, a 0.082Â VÂ ÃÂ 80Â ms strip peak potential (Es) was used to strip smaller metal nuclei partly, at last, a growth potential, â0.28Â V was applied to grow the nearly identical size slowly. Mechanism of copper electrodeposition on HOPG electrode from a solution of 1Â mM CuSO4 and 1.0Â M H2SO4 has been studied using cyclic voltammogram and chronoamperometry. In copper electrodeposition the charge-transfer step is fast and the rate of growth is controlled by the rate of mass transfer of copper ions to the growing centers. Reduction of Cu(II) ions did not undergo underpotential deposition. The initial deposition kinetics of Cu electrocrystallization corresponds to a model including progressive nucleation and diffusion controlled growth.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 262, Issues 1â3, 15 July 2005, Pages 125-131
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 262, Issues 1â3, 15 July 2005, Pages 125-131
نویسندگان
Ling Huang, Eun-Sung Lee, Kwang-Bum Kim,