کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9743388 | 1491189 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Rubeanic acid as novel carrier in construction of selective membrane sensor for La(III)
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new polyvinylchloride-based membrane of rubeanic acid as an ion carrier was fabricated using oleic acid as lipophilic additive. The best performance was exhibited by the membrane having composition rubeanic acid:PVC:OA:o-NPOE as 5:180:18:208 (w/w). The sensor exhibited a Nernstian response for La3+ over a wide concentration range of 3.2Â ÃÂ 10â8 to 1.0Â ÃÂ 10â2Â M with a detection limit of 2.5Â ÃÂ 10â8Â M. It showed response time of less than 15Â s and could be used for 5 months without any significant divergence. The proposed membrane sensor revealed good selectivity for La3+ over a wide variety of other metal ions and can be used in a pH range of 3.5-9.5 and in mixtures containing up to 30% (v/v) non-aqueous content. It was successfully used as an indicator electrode in the potentiometric titration of La(III) against EDTA.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 551, Issues 1â2, 17 October 2005, Pages 45-50
Journal: Analytica Chimica Acta - Volume 551, Issues 1â2, 17 October 2005, Pages 45-50
نویسندگان
A.K. Jain, A.K. Singh, Sameena Mehtab, Puja Saxena,