کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9759267 | 1497703 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen production in zirconia membrane reactors for use in PEM fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
A yttria-stabilized zirconia (YSZ) membrane was formed on the surface of a porous α-alumina support tube by a sol-gel procedure. The membrane was then impregnated with an aqueous solution of H2PtCl6 or RhCl3·3H2O and calcined in air at 500âC, to produce a Pt- or Rh-loaded YSZ membrane. Methane steam reforming (MSR) over the Rh-loaded Ce0.15Zr0.85O2 catalyst was carried out in a membrane reactor using the Pt-loaded YSZ membrane. Methane conversion in the membrane reactor was 20% higher than that in a packed bed reactor due to the high permeation rate of hydrogen compared to the reaction rate. In addition, Pt- and Rh-loaded YSZ membranes were also examined for the selective oxidation of CO from a mixture of H2and CO without any packed catalysts. When O2 was added to the feed, CO was oxidized in the Pt-loaded YSZ layer and the CO concentration of 10,000 ppm on the feed side was decreased to below 30 ppm (detection limit) at 150âC. Meanwhile the oxidation of CO was suppressed at higher temperatures because of the consumption of O2 as a result of the catalytic oxidation of H2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 30, Issue 9, August 2005, Pages 989-994
Journal: International Journal of Hydrogen Energy - Volume 30, Issue 9, August 2005, Pages 989-994
نویسندگان
Katsuki Kusakabe, Shibao Fumio, Tomokazu Eda, Masayoshi Oda, Ken-Ichiro Sotowa,