کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9769997 | 1501937 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Unusual isolation of a hemiaminal product from 4-cyclohexyl-3-thiosemicarbazide and di-2-pyridyl ketone: Structural and spectral investigations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Unusual isolation of a hemiaminal product from 4-cyclohexyl-3-thiosemicarbazide and di-2-pyridyl ketone: Structural and spectral investigations Unusual isolation of a hemiaminal product from 4-cyclohexyl-3-thiosemicarbazide and di-2-pyridyl ketone: Structural and spectral investigations](/preview/png/9769997.png)
چکیده انگلیسی
Stable hemiaminal product was isolated as single crystals from the condensation reaction of di-2-pyridyl ketone with 4-cyclohexyl-3-thiosemicarbazide and structurally and spectrochemically characterized. The compound is the first report of a stable hemiaminal product of the condensation reaction of a substituted thiosemicarbazone. Spectral characterization was carried out using IR, UV-vis., 1H NMR, 13C NMR, COSY and HMQC. The compound crystallizes into a triclinic lattice with space group P-1. The molecule reveals a highly strained ZE conformation and a one-dimensional packing is effected by a network of intermolecular hydrogen bonding interactions in the unit cell.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 749, Issues 1â3, 15 July 2005, Pages 177-182
Journal: Journal of Molecular Structure - Volume 749, Issues 1â3, 15 July 2005, Pages 177-182
نویسندگان
V. Suni, M.R. Prathapachandra Kurup, Munirathinam Nethaji,