کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9890899 | 1540340 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Microscopic structure of gelatin coacervates
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کلمات کلیدی
موضوعات مرتبط
علوم زیستی و بیوفناوری
بیوشیمی، ژنتیک و زیست شناسی مولکولی
زیست شیمی
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چکیده انگلیسی
Microscopic structure of simple coacervates of gelatin having concentration â¼130 g/l were studied at 25 °C by atomic force microscopy (AFM), rheology, small angle neutron scattering (SANS), UV absorption and circular dichroism (CD) techniques. The behavior of viscoelastic exponents Îâ² and Îâ³ of storage and loss modulii (Gâ²(Ï) â¼Â ÏÎâ², Gâ³(Ï) â¼Â ÏÎâ³) revealed that, Îâ²Â = 0.25 ± 0.01 and Îâ³Â = 0.78 ± 0.1 for coacervates. The mass fractal dimension 'df' for coacervate was found to be 2.27, which attributed a compact heterogeneous network structure to the coacervates. This is supported by AFM pictures. The CD and UV absorption data indicated presence of helical structures inside the coacervates phase. SANS results showed the existence of a single length scale associated with this system identified as gelatin persistence length, ζ = 27 ± 2 Ã
. These studies indicate that the coacervate phase is a low dimensional dense heterogeneous material comprised of strongly interconnected triple helices which imparts a large storage modulus to this material.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Biological Macromolecules - Volume 36, Issues 1â2, July 2005, Pages 39-46
Journal: International Journal of Biological Macromolecules - Volume 36, Issues 1â2, July 2005, Pages 39-46
نویسندگان
Biswaranjan Mohanty, H.B. Bohidar,