کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10274815 | 461735 | 2011 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reduction of high content of free fatty acid in sludge palm oil via acid catalyst for biodiesel production
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Reduction of high content of free fatty acid in sludge palm oil via acid catalyst for biodiesel production Reduction of high content of free fatty acid in sludge palm oil via acid catalyst for biodiesel production](/preview/png/10274815.png)
چکیده انگلیسی
In this study, sulphuric acid (H2SO4) was used in the pretreatment of sludge palm oil for biodiesel production by an esterification process, followed by the basic catalyzed transesterification process. The purpose of the pretreatment process was to reduce the free fatty acids (FFA) content from high content FFA (> 23%) of sludge palm oil (SPO) to a minimum level for biodiesel production (> 2%). An acid catalyzed esterification process was carried out to evaluate the low content of FFA in the treated SPO with the effects of other parameters such as molar ratio of methanol to SPO (6:1-14:1), temperature (40-80 °C), reaction time (30-120 min) and stirrer speed (200-800 rpm). The results showed that the FFA of SPO was reduced from 23.2% to less than 2% FFA using 0.75% wt/wt of sulphuric acid with the molar ratio of methanol to oil of 8:1 for 60 min reaction time at 60 °C. The results on the transesterification with esterified SPO showed that the yield (ester) of biodiesel was 83.72% with the process conditions of molar ratio of methanol to SPO 10:1, reaction temperature 60 °C, reaction time 60 min, stirrer speed 400 rpm and KOH 1% (wt/wt). The biodiesel produced from the SPO was favorable as compared to the EN 14214 and ASTM D 6751 standard.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel Processing Technology - Volume 92, Issue 5, May 2011, Pages 920-924
Journal: Fuel Processing Technology - Volume 92, Issue 5, May 2011, Pages 920-924
نویسندگان
Adeeb Hayyan, Md. Zahangir Alam, Mohamed E.S. Mirghani, Nassereldeen A. Kabbashi, Noor Irma Nazashida Mohd Hakimi, Yosri Mohd Siran, Shawaluddin Tahiruddin,