کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10275855 | 463405 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Encapsulated laccase electrodes for fuel cell cathodes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Biocatalysts are an attractive alternative to conventional noble metal catalysts for fuel cell cathodes. In principle, they combine the possibility of more efficient operation (lower intrinsic overpotential) with the benefits of renewability, selectivity and low temperature operation. In order for these benefits to be realized in a practical cathode design, however, both improved sources of suitable oxygen-reducing oxidoreductases, and improved electrode designs are required. In this paper, we discuss the preparation and performance of cathodes based on the “encapsulation” of a laccase enzyme with silica or organic polymer binders on porous carbon paper supports. We show that these electrodes are both electrochemically efficient and stable to leaching or degradation over millions of turnovers. We also show that these electrodes can be used with conventional Pt-based anodes in a direct methanol fuel cell structure.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 581, Issue 2, 1 August 2005, Pages 197-205
Journal: Journal of Electroanalytical Chemistry - Volume 581, Issue 2, 1 August 2005, Pages 197-205
نویسندگان
William E. Farneth, Michael B. D'Amore,