کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10547881 | 965393 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Fast isolation of hydrophobic organic environmental contaminants from exposed semipermeable membrane devices (SPMDs) prior to GC analysis
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کلمات کلیدی
SPMDs - SPMD هاOrganochlorine pesticides - آفت کش های ارگانو کلرهOctachlorostyrene - اکتاخلوستیرنAquatic ecosystem - اکوسیستم آبزیBrominated flame retardants - بازدارنده های شعله برومندPolychlorinated biphenyls - بیفنیل پلیکلر Musk compounds - ترکیبات ماوسSemipermeable membrane devices - دستگاه های غشایی نیمه رساناPolybrominated diphenyl ethers - دیفنیل اتر پلی بوروندیSampling - نمونهبرداریHexabromocyclododecane - هگزابروموسایلدودکان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Semipermeable membrane devices (SPMD) represent a passive sampling technology that is becoming widely used for monitoring of surface waters pollution. While “classic” procedures employ dialysis to recover target compounds from exposed SPMDs, in the present study analytes were isolated from cut membrane together with sequestering medium (triolein) using hexane as an extraction solvent. This approach allowed us to reduce the time needed for accomplishment of isolation step from 48Â h to only 1Â h. Automated gel permeation chromatography (GPC) clean-up is employed in the following step to separate triolein from analytes fraction. Musk compounds (MCs), polychlorinated biphenyls (PCBs), brominated flame retardants (BFRs) and several other persistent organochlorine compounds (OCs) were determined in the respective fraction by GC method employing selective detectors (MSD, ECD). As shown in a series of analyses of SPMDs deployed in various aquatic ecosystems, high recoveries and good repeatability of results together with a possibility to obtain the information on the pollution of sampling site at the day of sample arrival to laboratory make this newly implemented procedure an interesting alternative to time consuming dialysis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1092, Issue 2, 28 October 2005, Pages 170-181
Journal: Journal of Chromatography A - Volume 1092, Issue 2, 28 October 2005, Pages 170-181
نویسندگان
Lucie Å etková, Jana HajÅ¡lová, Per-Anders Bergqvist, VladimÃr Kocourek, Radek Kazda, Petr Suchan,