کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10575587 | 977521 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Palladium (II) complexes with mono-oxide 1,1â²-bis(diphenylphosphino)metallocene ligands [Fe(η5-C5Me4PPh2)(η5-C5Me4P{O}Ph2)] and [Os(η5-C5H4PPh2)(η5-C5H4P{O}Ph2)]
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Palladium (II) complexes with mono-oxide 1,1â²-bis(diphenylphosphino)metallocene ligands [Fe(η5-C5Me4PPh2)(η5-C5Me4P{O}Ph2)] and [Os(η5-C5H4PPh2)(η5-C5H4P{O}Ph2)] Palladium (II) complexes with mono-oxide 1,1â²-bis(diphenylphosphino)metallocene ligands [Fe(η5-C5Me4PPh2)(η5-C5Me4P{O}Ph2)] and [Os(η5-C5H4PPh2)(η5-C5H4P{O}Ph2)]](/preview/png/10575587.png)
چکیده انگلیسی
The monoxides [Fe(η5-C5Me4PPh2)(η5-C5Me4P{O}Ph2)] (1) and [Os(η5-C5H4PPh2)(η5-C5H4P{O}Ph2)] (2) have been prepared by treatment of the corresponding diphosphines with CCl4 and methanol. The 1 and 2 react with [Pd(PhCN)2Cl2] to give dichlorides [{Fe(η5-C5Me4PPh2)(η5-C5Me4P{O}Ph2)}PdCl2] (3) and [{Os(η5-C5H4PPh2)(η5-C5H4P{O}Ph2)}PdCl(μ-Cl)]2 (4) with κ2-P,O and κ1-P chelated ligands, correspondingly. The 3 and 4 were tested in catalytic amination and Suzuki type reactions of p-bromotoluene to show moderate activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 7, 30 March 2005, Pages 1710-1717
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 7, 30 March 2005, Pages 1710-1717
نویسندگان
Oleg V. Gusev, Tat'yana A. Peganova, Alexander M. Kalsin, Nikolai V. Vologdin, Pavel V. Petrovskii, Konstantin A. Lyssenko, Aleksei V. Tsvetkov, Irina P. Beletskaya,