کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1170381 960678 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
pH-resistant titania hybrid organic–inorganic sol–gel coating for solid-phase microextraction of polar compounds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
pH-resistant titania hybrid organic–inorganic sol–gel coating for solid-phase microextraction of polar compounds
چکیده انگلیسی

A novel titania-hydroxy-terminated silicone oil (titania-OH-TSO) sol–gel coating was developed for solid-phase microextraction of polar compounds. In general, titania-based sol–gel reaction is very fast and need to be decelerated by the use of suitable chelating agents. But in the present work, a judiciously designed sol solution ingredients was used to create the titania-OH-TSO coating without the addition of any chelating agent, which simplified the sol–gel procedure. Thanks to the variety of titania's adsorption sites and their acid–base characteristics, aromatic amines, phenols and polycyclic aromatic hydrocarbons were efficiently extracted and preconcentrated from aqueous samples followed by thermal desorption and GC analysis. The newly developed sol–gel hybrid titania coating demonstrated excellent pH stability, and retained its extraction characteristics intact even after continuous rinsing with a 3 M HCl or NaOH solution for 12 h. Furthermore, it could withstand temperatures as high as 320 °C. Practical application was demonstrated through the analysis of six aromatic amines in dye process wastewater. A linearity of four orders of magnitude was obtained with correlation coefficient better than 0.9982. The detection limits ranged from 0.22 to 0.84 μg L−1 and the repeatability of the measurements was <7.0%. The recoveries of these compounds studied in the wastewater were in the ranges 83.6–101.4%, indicating the method accuracy.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 590, Issue 1, 2 May 2007, Pages 26–33
نویسندگان
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