کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300475 1498822 2007 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Homogeneous catalysis of platinum(II) complexes in photochemical hydrogen production from water
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Homogeneous catalysis of platinum(II) complexes in photochemical hydrogen production from water
چکیده انگلیسی

This review concentrates on the Pt(II)-catalyzed reduction of water into molecular hydrogen, with emphasis given to the works undertaken thus far by the authors’ group. The homogeneous catalysis of (i) dinuclear platinum(II) complexes, (ii) mononuclear platinum(II) complexes, (iii) platinum(II) complexes having electron-acceptor groups, and (iv) platinum(II) complexes having photosensitizing groups is described. The dependences of the H2-evolving activity on the metal–metal interaction, the Pt(II) dz2dz2 orbital energy, the steric factor, and the electron-acceptor ability are discussed. Moreover, the first active model of a photo-hydrogen-evolving molecular device made up of a tris(2,2′-bipyridine)ruthenium(II) derivative and a homogeneous platinum(II) catalyst is discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 251, Issues 21–24, November 2007, Pages 2753–2766
نویسندگان
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