کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300538 1498839 2006 21 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Group 10 transition-metal complexes with metal–silicon bonds derived from 1,2-disilylbenzenes and bis(2-silylphenyl)silane
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Group 10 transition-metal complexes with metal–silicon bonds derived from 1,2-disilylbenzenes and bis(2-silylphenyl)silane
چکیده انگلیسی

This article provides an account of the group 10 transition-metal complexes with metal–silicon bonds formed by the reaction of hydrosilanes with group 10 transition-metal complexes, with particular emphasis on the unique chemistry of 1,2-disilylbenzene, 1-dimethylsilyl-2-silylbenzene and bis(2-silylphenyl)silane. These hydrosilanes provide sterically less congested bidentate and tridentate silyl ligands and make it possible to stabilize a number of unusual mono-, di- and trinuclear poly(silyl) group 10 metal complexes including those of high formal valence state.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 250, Issues 9–10, May 2006, Pages 991–1011
نویسندگان
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