کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326327 | 977425 | 2007 | 10 صفحه PDF | دانلود رایگان |

Within this study, coordination properties of the cyclic diphosphine 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine (bedip) are investigated, through the preparation of neutral and cationic Pt(II), Pt(IV) and Pd(II) complexes. The diphosphine acts as bridging ligand in the neutral Pt(II) and Pd(II) complexes, affording [MX(CH3)(μ-bedip)]2 (X = Cl, Br, I, CH3) species. Chelation is observed in all the remaining complexes. The molecular structures of [PtX(CH3)(μ-bedip)]2 (X = Br, I) and [PtI(CH3)3(bedip)] are also determined.
Versatile coordination features of 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine (bedip) are disclosed by preparing neutral and cationic Pt(II), Pt(IV) and Pd(II) complexes. Spectroscopic and structural characterizations are reported along with preliminary reactivity investigations.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 23, 1 November 2007, Pages 5211–5220