کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1326327 977425 2007 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Coordination modes of 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine (bedip) to Pt and Pd metal ions: Synthesis and structural characterization of mono- and bi-nuclear complexes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Coordination modes of 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine (bedip) to Pt and Pd metal ions: Synthesis and structural characterization of mono- and bi-nuclear complexes
چکیده انگلیسی

Within this study, coordination properties of the cyclic diphosphine 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine (bedip) are investigated, through the preparation of neutral and cationic Pt(II), Pt(IV) and Pd(II) complexes. The diphosphine acts as bridging ligand in the neutral Pt(II) and Pd(II) complexes, affording [MX(CH3)(μ-bedip)]2 (X = Cl, Br, I, CH3) species. Chelation is observed in all the remaining complexes. The molecular structures of [PtX(CH3)(μ-bedip)]2 (X = Br, I) and [PtI(CH3)3(bedip)] are also determined.

Versatile coordination features of 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine (bedip) are disclosed by preparing neutral and cationic Pt(II), Pt(IV) and Pd(II) complexes. Spectroscopic and structural characterizations are reported along with preliminary reactivity investigations.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 23, 1 November 2007, Pages 5211–5220
نویسندگان
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