کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1329812 | 1500092 | 2015 | 5 صفحه PDF | دانلود رایگان |
• A simple fabrication method for highly aligned LGO/PDMS composites is proposed.
• LGO aqueous dispersion shows nematic liquid crystalline phase at 0.8 mg/ml.
• In nematic phase, LGO flakes are highly aligned by geometric confinement.
• Infiltration of PDMS into freeze-dried LGO allows highly aligned LGO/PDMS composites.
Graphene is an emerging graphitic carbon materials, consisting of sp2 hybridized two dimensinal honeycomb structure. It has been widely studied to incorporate graphene with polymer to utilize unique property of graphene and reinforce electrical, mechanical and thermal property of polymer. In composite materials, orientation control of graphene significantly influences the property of composite. Until now, a few method has been developed for orientation control of graphene within polymer matrix. Here, we demonstrate facile fabrication of high aligned large graphene oxide (LGO) composites in polydimethylsiloxane (PDMS) matrix exploiting liquid crystallinity. Liquid crystalline aqueous dispersion of LGO is parallel oriented within flat confinement geometry. Freeze-drying of the aligned LGO dispersion and subsequent infiltration with PDMS produce highly aligned LGO/PDMS composites. Owing to the large shape anisotropy of LGO, liquid crystalline alignment occurred at low concentration of 2 mg/ml in aqueous dispersion, which leads to the 0.2 wt% LGO loaded composites.
Liquid crystalline LGO aqueous dispersions are spontaneous parallel aligned between geometric confinement for highly aligned LGO/polymer composite fabrication.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 224, April 2015, Pages 115–119