کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1332376 1500115 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Boric acid flux synthesis, structure and magnetic property of MB12O14(OH)10 (M=Mn, Fe, Zn)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Boric acid flux synthesis, structure and magnetic property of MB12O14(OH)10 (M=Mn, Fe, Zn)
چکیده انگلیسی

Three new borates MB12O14(OH)10 (M=Mn, Fe, Zn) have been synthesized by boric acid flux methods, which are isotypic to NiB12O14(OH)10. Single-crystal XRD was performed to determine the crystal structures in detail. They all crystallize in the monoclinic space group P21/c. The size of MO6 (M=Mg, Mn, Fe, Co, Ni, Zn) octahedron shows a good agreement with the Shannon effective ionic radii of M2+. Magnetic measurements indicate MnB12O14(OH)10 is antiferromagnetic without a long-range ordering down to 2 K. The values of its magnetic superexchange constants were evaluated by DFT calculations, which explain the observed magnetic behavior. The UV–vis diffuse reflectance spectrum of ZnB12O14(OH)10 suggests a band gap ∼4.6 eV. DFT calculations indicate it has a direct band gap 4.9 eV. The optical band gap is contributed by charge transfers from the occupied O 2p to the unoccupied Zn 4s states.

Experimental and theoretical studies indicate MnB12O14(OH)10 is antiferromagnetic without a long-range ordering. DFT calculations show ZnB12O14(OH)10 has a direct band gap of 4.9 eV. Figure optionsDownload as PowerPoint slideHighlights
► MB12O14(OH)10 (M=Mn, Fe, Zn) are synthesized by two-step boric acid flux method.
► Single-crystal XRD was performed to determine the crystal structures in detail.
► Size of MO6 (M=Mg, Mn, Fe, Co, Ni, Zn) agrees with the effective ionic radii.
► MnB12O14(OH)10 is antiferromagnetic without a long-range ordering down to 2 K.
► DFT calculations indicate ZnB12O14(OH)10 has a direct band gap 4.9 eV.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 201, May 2013, Pages 29–34
نویسندگان
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