Study of the surface chemistry and morphology of single walled carbon nanotube–magnetite composites

The study of the morphologies of the single walled carbon nanotube (SWCNT), magnetite nanoparticles (MNP), and the composite based on them was carried with combined X-ray diffraction (XRD), Raman spectroscopy (RS), scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM) and high resolution transmission electron microscopy (HRTEM). These techniques together with thermogravimetric analyses (TGA) and diffuse reflectance infrared transform spectroscopy (DRIFTS) confirmed the production of pure single phases, and that the composite material consisted of MNP attached to the outer surface of the SWCNT. The Mössbauer spectroscopy (MS) research showed the presence of a large quantity of Lewis acid sites in the highly dispersed magnetite particles supported on the SWCNT outer surface. The DRIFTS carbon dioxide adsorption study of the composites revealed significant adsorption of carbon dioxide, fundamentally in the Lewis acid sites. Then, the Lewis acid sites were observed to be catalytically active. Further, the electron exchange between the Lewis acid sites and the basic or amphoteric adsorbed molecules could influence the magnetic properties of the magnetite. Consequently, together with this first ever use of MS in the study of Lewis acid sites, this investigation revealed the potential of the composites for catalytic and sensors applications.

A large amount of Lewis acid sites were found in the highly dispersed magnetite which is supported on the SWCNT outer surface.Figure optionsDownload as PowerPoint slideResearch highlights
► The obtained materials were completely characterized with XRD, Raman and SEM–TEM.
► DRIFT, TGA and adsorption of the composites allowed understand the material formation.
► This is the first report of a study of Lewis sites by Mössbauer spectroscopy.