کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1401279 | 1501704 | 2016 | 6 صفحه PDF | دانلود رایگان |
• FTIR, NMR, XRD and SEM-EDX were used to elucidate the title compound.
• The structure of the title compound exhibits C–H···Ni anagostic interactions.
• The anagostic interactions are supported by the spectroscopic data.
• The complex decomposes at ∼330 °C in a single step to produce NiS nanoparticles.
The molecular structure of bis(κ2S,Sʹ-di(isopropyl)dithiocarbamato)nickel(II) has been examined by single crystal X-ray diffraction. The data reveal a C–H⋅⋅⋅Ni anagostic interaction arising from the interaction of two non-equivalent molecules within the crystal. Thermal analysis data show that the complex decomposes at ∼330 °C. The structure of the resultant NiS material was examined using scanning electron microscopy and energy dispersive X-ray spectroscopy which revealed NiS nanowires.
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Journal: Journal of Molecular Structure - Volume 1113, 5 June 2016, Pages 127–132