کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1405540 | 1501749 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Novel arylated chloro- and methoxy-1,3-dibutadienes: Influence of substituents on molecular conformation and crystal packing
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Three novel arylated chloro- and methoxy-1,3-butadienes were prepared and studied by a combination of spectroscopic (UV/vis, IR and NMR) and X-ray crystallographic methods. Influence of substituent on the molecular conformation and crystal packing (i.e. intermolecular interactions) was studied. It was predicted that the differences in electronic and steric effects of two chlorine atoms in comparison to two methoxy groups as substituents at different locations in the molecule would provide various packing of the molecules and cause different assumptions for the photochemical behaviour.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1068, 25 June 2014, Pages 124-129
Journal: Journal of Molecular Structure - Volume 1068, 25 June 2014, Pages 124-129
نویسندگان
Dragana Vuk, KreÅ¡imir MolÄanov, Irena Å koriÄ,