کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1406446 1501830 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
X-ray scattering study of liquid acetic acid: Is the short crystal structure reproduced in the liquid?
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
X-ray scattering study of liquid acetic acid: Is the short crystal structure reproduced in the liquid?
چکیده انگلیسی
A structural investigation of liquid acetic acid was performed at 298 K using X-ray scattering. To extract the molecular form factor F1(q), the geometry of the conformer which has been found in the crystal is considered. The pair correlation function clearly shows the signature of hydrogen bonding interactions in liquid acetic acid. The crystal O-H⋯O distance is taken into account and the number of H-bond(s) is assumed to be equal to one and two. The liquid structure can be described by a chain-like trimer similar to the one existing in the crystal; the structure factor SM(q) extracted from such a cluster where the interactions with neighbouring chains is considered fairly agrees with the experimental one beyond q = 2 Å−1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 984, Issues 1–3, 15 December 2010, Pages 170-175
نویسندگان
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