کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1408172 | 1501907 | 2007 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Anion-dependent selective formation of intermolecular non-covalent bonds
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
The crystal structures and packings of bis(pyridiniopropyl)benzene derivatives, [1,4-(4-R-C5H4N+CH2CH2CH2)2C6H4](PF6)2 (1, R = H; 2, R = tert-Bu), were investigated by X-ray diffraction studies. In compound 1, two pyridiniopropyl chains attached at the para positions of the phenylene group are in a linear conformation, and the central phenylene ring forms an intermolecular acceptor-donor-acceptor Ï-Ï stacking with neighboring two pyridinium rings. Compound 2 also has a linear conformation similar to 1, but intermolecular Ï-Ï stackings were not observed in the crystal stackings of 2. Instead, there is found a C-H â¯Â Ï interaction between the central phenylene ring and one of the hydrogen atoms in the tert-Bu group linked at the 4 position of pyridinium ring. The difference of the packing modes between 1 and 2 apparently results from steric hindrance caused by bulkiness of the substituents and counter anions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 829, Issues 1â3, 17 March 2007, Pages 168-175
Journal: Journal of Molecular Structure - Volume 829, Issues 1â3, 17 March 2007, Pages 168-175
نویسندگان
Kanako Tsutsui, Take-aki Koizumi, Koji Tanaka, Hideki Hayashi,