کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1408985 | 1501708 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Self association of α-tocopherol in solutions. Infrared absorption and theoretical study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The IR spectra of α-tocopherol (α-T) solutions in CCl4 at different concentrations (0.0009-0.5 M) and temperatures from 15 to 50 °C were recorded. The formation of relatively weak and broad red-shifted band arising with increasing of α-T concentration was observed. The band was attributed to the formation of α-T H-bonded oligomers. The resolution of the complex band and DFT calculation of oligomers molecular structure, energy and IR spectra were performed. As a result the experimental IR spectra, equilibrium constants, the most probable structures of oligomers and H-bond energies were found.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1109, 5 April 2016, Pages 74-81
Journal: Journal of Molecular Structure - Volume 1109, 5 April 2016, Pages 74-81
نویسندگان
E.I. Finkelshtein, T.A. Morozova, R.S. Shamsiev, E.A. Belozertseva, E.A. Katsman,