کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1447190 988638 2011 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Low-temperature hydrogen desorption and the structural properties of spark discharge generated Mg nanoparticles
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Low-temperature hydrogen desorption and the structural properties of spark discharge generated Mg nanoparticles
چکیده انگلیسی

Mg nanoparticles were synthesized using spark discharge, resulting in large-scale structures of agglomerated nanoparticles with primary particle sizes of ∼10 nm, surrounded by MgO shells 1–2 nm thick. Thermal hydrogen desorption starts at remarkably low temperatures of ∼350 K, related to the small sizes of particles, and extends over a broad temperature range to beyond 700 K, caused by the presence of oxide shells acting as activation barriers. The hydrogen sorption kinetics is increased significantly by adding Pd nanoparticles in situ during synthesis, showing the versatility of spark discharge generation for the production of metal hydride nanocomposites.

Research highlights
► Spark discharge generated Mg nanoparticles form large-scale agglomerated structures.
► The small size of MgH2 nanoparticles leads to low temperature hydrogen desorption.
► The hydrogen desorption is characterized by a wide range of apparent activation energies.
► Pd nanoparticles added in-situ by a second spark generator induce faster kinetics.
► Spark discharge generation shows great promise to create metal hydride nanocomposites.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Acta Materialia - Volume 59, Issue 8, May 2011, Pages 3070–3080
نویسندگان
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